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ChemInform Abstract: Generation of Allenic Samarium Complexes from Propargylic Ethers and ( C5Me5)2Sm(thf)2, and Their Electrophilic Trapping.

✍ Scribed by Y. MAKIOKA; K. KOYAMA; T. NISHIYAMA; K. TAKAKI; Y. TANIGUCHI; Y. FUJIWARA


Book ID
112023733
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regio- and Stereoch
✍ K. TAKAKI; T. KUSUDO; S. UEBORI; T. NISHIYAMA; T. KAMATA; M. YOKOYAMA; K. TAKEHI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 41 KB πŸ‘ 2 views

Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf )n. -The reductive cleavage of the C-O bond of allylic benzyl ethers with Sm(C 5 Me 5 ) 2 (thf) 2 leads to substituted allylic Sm complex intermed