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Synthesis and structure of mono-THF solvates of bis(cyclopentadienyl)samarium(II) complexes: (C5Me5)2 Sm(THF) and [C5H2(SiMe 3)3][C5H3(SiMe3)2]Sm(THF)

✍ Scribed by William J. Evans; Gabriele Kociok-Köhn; Samuel E. Foster; Joseph W. Ziller; Robert J. Doedens

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
547 KB
Volume
444
Category
Article
ISSN
0022-328X

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New Alkali Metal Boratabenzenes: Structu
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✍ Xiaolai Zheng; Gerhard E. Herberich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB

## Abstract The potassium salt K(C~5~H~5~BMe) (8) can be obtained from 2‐(Me~3~Sn)C~5~H~5~BMe (7)/KO__t__Bu in toluene in essentially quantitative yield. Metalation of 1‐(dimethylamino)‐3‐methylene‐1,2,3,6‐tetrahydroborinine (9) with MN(SiMe~3~)~2~ (M = Na, K) in toluene afforded the unsolvated sal