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Reductive opening of cyclopropylogous α-hydroxy aldehydes and ketones by samarium(II) iodide

✍ Scribed by Alex Nivlet; Valérie Le Guen; Luc Dechoux; Thierry Le Gall; Charles Mioskowski

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
198 KB
Volume
39
Category
Article
ISSN
0040-4039

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## Functionalized cyclopropyl ketones have been found to undergo facile reductive cyclopropane ring opening with samarium (II) diiodide in the presence of a proton source. These reactions were exceedingly rapid, taking place in most cases at -78°C under neutral conditions. An ester group substitut