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ChemInform Abstract: Reductive Opening of Cyclopropylogous α-Hydroxy Aldehydes and Ketones by Samarium(II) Iodide.

✍ Scribed by A. NIVLET; V. LE GUEN; L. DECHOUX; T. LE GALL; C. MIOSKOWSKI

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reductive Opening of Cyclopropylogous α-Hydroxy Aldehydes and Ketones by Samarium(II) Iodide.

-The regioselectivity of the title reaction is found to be strongly dependant on the substitution pattern of the substrate. In several cases, a tandem cyclopropyl opening-deoxygenation reaction leads to γ-carbonyl alkenes.

-(NIVLET, A.

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