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ChemInform Abstract: Intramolecular and Intermolecular Ketone—Ester Reductive Coupling Reactions Promoted by Samarium(II) Iodide.

✍ Scribed by Yunkui Liu; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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Intramolecular Ketone-Nitrile Reductive Coupling Reactions Promoted by Samarium(II) Iodide. -The photochemically induced reaction of keto nitriles of type (I), (III), and (V) with SmI 2 offers an efficient route to prepare monocyclic, fused bicyclic, and bridged α-hydroxy ketones. 5-exo-Coupling pr