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Reductive alkylation of α-cyano ketones induced by samarium iodide

✍ Scribed by Jia-Liang Zhu; Kak-Shan Shia; Hsing-Jang Liu

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 173 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01470-7

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✦ Synopsis

SmI2-HMPA was shown to be an effective reagent for reductive alkylation of 0t-cyano ketones, a useful process for regiocontrol of et,et-dialkylation of ketones.

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