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Lithium naphthalenide induced reductive alkylation of α-cyano ketones. A general method for regiocontrol of α, α-dialkylation of ketones

✍ Scribed by Hsing-Jang Liu; Jia-Liang Zhu; Kak-Shan Shia

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
188 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

An efficient general method for the consecutive introduction of two alkyl groups to the ct carbon of a ketone carbonyl has been developed, making use of the lithium naphthalenide induced reductive alkylation of an ~t-cyano ketone system as a key operation.

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SmI2-HMPA was shown to be an effective reagent for reductive alkylation of 0t-cyano ketones, a useful process for regiocontrol of et,et-dialkylation of ketones.

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