𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reductive ring opening of cyclopropyl ketones with samarium (II) diiodide

✍ Scribed by Yong Hae Kim; In Sang Lee

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
288 KB
Volume
3
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Functionalized cyclopropyl ketones have been found to undergo facile reductive cyclopropane ring opening with samarium (II)

diiodide in the presence of a proton source. These reactions were exceedingly rapid, taking place in most cases at -78Β°C under neutral conditions. An ester group substituted at the C2 position of the cyclopropane ring played an important role in the ring opening of cyclopropyl ketones.

πŸ“œ SIMILAR VOLUMES

Samarium Diiodide Induced Reactions of C
Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1,8-Diketones β€” Scope, Limitations, Mechanisms.
✍ Francesca Aulenta; Alexandra Hoelemann; Hans-Ulrich Reissig πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 25 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.