The reaction of (Z)-l-halo-l-alkenyldialkylborane (1) with tributyltin hydride (n-BuaSnH) at 0 \*C or room temperature results in reduetive removal of the halogen atom to afford (E)-or (Z)-l-aikenyldialkylborane whose stereochemistry depends on the dialkylboryl group and the alkenyl group of 1.
Reductive dehalogenation of polyhalofluorocarbons with tributyltin hydride
โ Scribed by Michael Van Der Puy; Randolph K. Belter; Ralph J. Borowski; Lois A.S. Ellis; Phillip J. Persichini III; Andrew J. Poss; Theodore P. Rygas; Harry S. Tung
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 455 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-1139
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