1,3-syn diastereoselective reduction of β-hydroxyketones with diisobutylaluminum hydride and tributyltin hydride
✍ Scribed by Syun-ichi Kiyooka; Hisanori Kuroda; Yayoi Shimasaki
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 196 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Hydroxyketones and diketones have been reduced with lithium indium hydride to give meso-diols selectively, c¢-Hydroxyketones and 0c-diketones are reduced to meso-l,2-diols with high diastereoselectivities, whereas the selectivities of ~hydroxyketones and [~diketones are less satisfactory.
Nitroalkenes upon treatment with tributyltin hydride in the absence of any catalyst provide a new method for the reduction of 4 B-unsaturated nitrocompounds. Oxidative cleavage of the intermediate stannyl nitronates yielded carbonyl compounds in good yields.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v