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Reduction of α,β-unsaturated nitrocompounds with tributyltin hydride.

✍ Scribed by J.M. Aizpurua; M. Oiarbide; C. Palomo

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
166 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

Nitroalkenes upon treatment with tributyltin hydride in the absence of any catalyst provide a new method for the reduction of 4 B-unsaturated nitrocompounds. Oxidative cleavage of the intermediate stannyl nitronates yielded carbonyl compounds in good yields.

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