Reductive Cleavage of the Te—Te Bond in Ditellurides by CeCl3/Sm System: A Novel Method for the Synthesis of β-Telluroesters (and Nitriles).
✍ Scribed by Xue Li; Songlin Zhang; Yulu Wang; Yongmin Zhang
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 90 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Phentyltellurotrimethylsilane (1) was reduced by samarium diiodide in tetrahydrofuran (THF) to produce samarium phenyltellurolate. This new tellurolate anion reacted smoothly with alkyl and benzyl halides to give alkyl and benzyl-phenyl tellurides in good yields under mild and neutral conditions. Th