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ChemInform Abstract: Reductive Cleavage of Te—Te Bond in Ditellurides by Sm/ZrCl4 System: A Novel Method for the Synthesis of β-Telluroesters (and Nitriles).

✍ Scribed by Songlin Zhang; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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Phentyltellurotrimethylsilane (1) was reduced by samarium diiodide in tetrahydrofuran (THF) to produce samarium phenyltellurolate. This new tellurolate anion reacted smoothly with alkyl and benzyl halides to give alkyl and benzyl-phenyl tellurides in good yields under mild and neutral conditions. Th