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Reductive Cleavage of the Se—Se Bond in Diselenides by the CeCl3/Sm System: A Novel Method for the Synthesis of Selenoesters.

✍ Scribed by Xue Li; Songlin Zhang; Yulu Wang; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2003
Weight
93 KB
Volume
34
Category
Article
ISSN
0931-7597

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Reductive cleavage of the Se–Se bond in
Reductive cleavage of the Se–Se bond in diselenides by the Sm/HgCl2 system: Formation and reactions of samarium selenolates
✍ Lei Wang; Yongmin Zhang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

Treatment of diaryl diselenides and dialkyl diselenides with metallic samarium and mercury (II) chloride in tetrahydrofuran conveniently gave samarium arylselenolates and alkylselenolates. These "living" species reacted with acyl chlorides, acid anhydrides, methyl chloroformate, organic halides, epo