𝔖 Bobbio Scriptorium
✦   LIBER   ✦

CeCl3/Sm Induced Reductive Cleavage of the S—S Bond in Disulfide: A Novel Method for the Synthesis of β-Thioesters, Thiol-esters and Alkylphenyl Sulfides.

✍ Scribed by Xue Li; Songlin Zhang; Yongmin Zhang


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Samarium diiodide induced reductive clea
✍ Songlin Zhang; Yongmin Zhang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB 👁 2 views

Phentyltellurotrimethylsilane (1) was reduced by samarium diiodide in tetrahydrofuran (THF) to produce samarium phenyltellurolate. This new tellurolate anion reacted smoothly with alkyl and benzyl halides to give alkyl and benzyl-phenyl tellurides in good yields under mild and neutral conditions. Th