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Reductive carboxylation of alkyl halides with CO2 by use of photoinduced SmI2/Sm reduction system

✍ Scribed by Akihiro Nomoto; Yusuke Kojo; Go Shiino; Yuri Tomisaka; Ikuko Mitani; Masahiko Tatsumi; Akiya Ogawa

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
930 KB
Volume
51
Category
Article
ISSN
0040-4039

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Reductive coupling of allylic acetates w
Reductive coupling of allylic acetates with carbonyl compounds by using Pd(0)-SmI2 system
✍ Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 123 KB

Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O1 to yield homoallylic alcohols. ## In a previous paper we reported the Pd(O)-catalyzed reduction of allylic acetates with Sm12 and Z-propanol.