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Reductive Coupling of Allylic Esters with Carbonyl Compounds Mediated by the Mischmetall/[SmI2/Pd0cat.′]cat. System

✍ Scribed by Sédami Médégan; Florence Hélion; Jean-Louis Namy


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
136 KB
Volume
2005
Category
Article
ISSN
1434-193X

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Reductive coupling of allylic acetates w
✍ Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 123 KB

Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O1 to yield homoallylic alcohols. ## In a previous paper we reported the Pd(O)-catalyzed reduction of allylic acetates with Sm12 and Z-propanol.