Reductive coupling of allylic acetates with carbonyl compounds by using Pd(0)-SmI2 system

✍ Scribed by Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi

• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 123 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)84214-8

✦ Synopsis

Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O1 to yield homoallylic alcohols.

In a previous paper we reported the Pd(O)-catalyzed reduction of allylic acetates with

Sm12 and Z-propanol.