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Reduction of allylic acetates by using a novel Pd(O)-SmI2 system

✍ Scribed by Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
136 KB
Volume
27
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Reductive coupling of allylic acetates w
Reductive coupling of allylic acetates with carbonyl compounds by using Pd(0)-SmI2 system
✍ Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 123 KB

Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O1 to yield homoallylic alcohols. ## In a previous paper we reported the Pd(O)-catalyzed reduction of allylic acetates with Sm12 and Z-propanol.

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## Abstract The combinations promote the reaction of cyclic hemiacetals with primary amines to generate cyclic hemiacetals which are in equilibrium with ω‐hydroxyimines.