Reduction of some Cyclic Amides by Lithium Aluminium Hydride
β Scribed by DE MAYO, P.; RIGBY, W.
- Book ID
- 109563608
- Publisher
- Nature Publishing Group
- Year
- 1950
- Tongue
- English
- Weight
- 101 KB
- Volume
- 166
- Category
- Article
- ISSN
- 0028-0836
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π SIMILAR VOLUMES
Although lithium alumlnium hydride is known to be effective In reducing certain types of organo-sulphur compounds, its action on compounds having the linkage -CC-S-or -CS-Sdoes not appear to have been extensively studied. Newman and his co-workers obtained difluorodecanol by the reduction of ethyl d
Unsubstituted medium-ring 1,2-epoxycycloalkanes and certain vie-epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAIH, alone is used as reducing agent. However, the combination of LiA1H4 and AICI,, in a 2:l molar ratio (with respect to 1 mol-equiv. of epoxide) used in refluxi