only a few reductions of aromatic halides with lithium aluminum hydride have been reported. For example, three hour reflux of p-bromotoluene in tetrahydrofuran with a mixture of lithium slumlnum hydride and lithium hydride (1) yields 14% toluene; g-chloroiodobenzene \* Fellow of the Alfred P. Sloan
Lithium aluminium hydride reduction of some organo-sulphur compounds.
✍ Scribed by Kazi Abdul Latif; Paritosh Kumar Chakraborty
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 152 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Although lithium alumlnium hydride is known to be effective In reducing certain types of organo-sulphur compounds, its action on compounds having the linkage -CC-S-or -CS-Sdoes not appear to have been extensively studied. Newman and his co-workers obtained difluorodecanol by the reduction of ethyl dlfluorothiodecanoate with LIAlH,, and they reported
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## Abstract The factors influencing the ease of the lithium aluminium hydride reduction of various 1,2‐epoxycycloalkanes and 1,2‐epoxyalkanes are described and discussed.
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