Reduction of aromatic halides with lithium aluminium hydride
β Scribed by Gerasimos J. Karabatsos; Robert L. Shone; Stuart E. Scheppele
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 157 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
only a few reductions of aromatic halides with lithium aluminum hydride have been reported. For example, three hour reflux of p-bromotoluene in tetrahydrofuran with a mixture of lithium slumlnum hydride and lithium hydride (1) yields 14% toluene; g-chloroiodobenzene * Fellow of the Alfred P. Sloan Foundation.
π SIMILAR VOLUMES
Although lithium alumlnium hydride is known to be effective In reducing certain types of organo-sulphur compounds, its action on compounds having the linkage -CC-S-or -CS-Sdoes not appear to have been extensively studied. Newman and his co-workers obtained difluorodecanol by the reduction of ethyl d