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The Reduction of Some 1, 2-Epoxides with Lithium Aluminium Hydride. Preliminary Communication

✍ Scribed by Milhailo Lj. Mihailović; Vladimir Andrejević; Jovan Milovanović; Jovan Janković

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
208 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The factors influencing the ease of the lithium aluminium hydride reduction of various 1,2‐epoxycycloalkanes and 1,2‐epoxyalkanes are described and discussed.

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The Reductive Conversion of Some Cyclic
The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride
✍ Vladimir Andrejević; Mira Bjelaković; Milan M. Mihailović; Mihailo Lj. Mihailovi 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 172 KB

Unsubstituted medium-ring 1,2-epoxycycloalkanes and certain vie-epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAIH, alone is used as reducing agent. However, the combination of LiA1H4 and AICI,, in a 2:l molar ratio (with respect to 1 mol-equiv. of epoxide) used in refluxi