We have recently reported that lithium aluminlum hydride (LAH), contrary to expectations of long standlng, can bring about reductive dehalogenatlon of a wide variety of so-called Inert organic halldes in high yields (>8O%)l. In par-
Dechlorination of o-chloronitrobenzene by lithium aluminium hydride reduction
β Scribed by H. A. B. Linke; R. Bartha; D. Pramer
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 119 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0028-1042
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π SIMILAR VOLUMES
only a few reductions of aromatic halides with lithium aluminum hydride have been reported. For example, three hour reflux of p-bromotoluene in tetrahydrofuran with a mixture of lithium slumlnum hydride and lithium hydride (1) yields 14% toluene; g-chloroiodobenzene \* Fellow of the Alfred P. Sloan
Although lithium alumlnium hydride is known to be effective In reducing certain types of organo-sulphur compounds, its action on compounds having the linkage -CC-S-or -CS-Sdoes not appear to have been extensively studied. Newman and his co-workers obtained difluorodecanol by the reduction of ethyl d