Reduction by a model of NAD(P)H. 44. Transition metal catalyzed reduction of allylic acetate
โ Scribed by Kaoru Nakamura; Atsuyoshi Ohno; Shinzaburo Oka
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 126 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In spite of tremendous works on mimetic reactions of NAD(P)H-dependent dehydrogenases, 1 stereochemical problem has not been paid much attention. Recently, we reported that optically active 1,4-dihydronicotinamide derivatives, in which the chiral center is separated from the reaction center by five
With respect to enzymatic reductions of carbonyl compounds by reduced pyridine nucleotides,NAD(P)H,wedescribedpreviouslychemicalreduction, assisted by a divalent metal ion such as Mg++ or Zn ++,of a-keto esters with 1-benzyl-1,4dihydronicotinamide(BNAH) as a model of NAD(P)H'! This mimicry has beene