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NAD(P)+-NAD(P)H model. 52. Reduction of olefins by hantzsch ester on silica gel

โœ Scribed by Kaoru Nakamura; Masayuki Fujii; Atsuyoshi Ohno; Shinzaburo Oka


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
252 KB
Volume
25
Category
Article
ISSN
0040-4039

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Hydride transfer mechanisms of the reductions of xanthylium ion by NAD(P)H analogues (i.e. BNAH, HEH and AcrH 2 ) were investigated. Both the kinetic observations and an analysis of thermodynamic driving forces for each mechanistic step in all the possible mechanisms indicate that the reductions are