Reduction and selective oxo group silylation of the uranyl dication
β Scribed by Arnold, Polly L.; Patel, Dipti; Wilson, Claire; Love, Jason B.
- Book ID
- 109897152
- Publisher
- Nature Publishing Group
- Year
- 2008
- Tongue
- English
- Weight
- 400 KB
- Volume
- 451
- Category
- Article
- ISSN
- 0028-0836
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π SIMILAR VOLUMES
## Experimental Section Synthetic procedures and characterizing data. 3: To a solution of 2 (250 mg, 0.21 mmol) in pyridine was added 1.9 equivalents of HCl in Et 2 O (2.0 mL, 0.4 mmol). The resulting suspension was stirred for 2 h, after which the precipitate was isolated and dried under vacuum,
The group selective reductive cleavage of benzylidene acetals derived from dials containing chains equipped with a central chirotopic, nonstereogenic carbon atom is reported. The stereochemistry that is obtained at the central carbon is suitable for application to the synthesis of members of the str