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Redox-Active Behavior of the [{Ti(η 5 -C 5 Me 5 )(μ-NH)} 3 (μ 3 -N)] Metalloligand

✍ Scribed by Caballo, Jorge; Carbó, Jorge J.; Mena, Miguel; Pérez-Redondo, Adrián; Poblet, Josep-M.; Yélamos, Carlos

Book ID: 126593144
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 966 KB
Volume: 52
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic400463a

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## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i

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