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Discovering the chemical reactivity of the molecular oxonitride [{Ti(η5-C5Me5)(μ-O)}3(μ3-N)]

✍ Scribed by Sonia Aguado-Ullate; Jorge J. Carbó; Octavio González-del Moral; María Gómez-Pantoja; Alberto Hernán-Gómez; Avelino Martín; Miguel Mena; Josep.-M. Poblet; Cristina Santamaría

Book ID: 116680096
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 658 KB
Volume: 696
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2011.06.023

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## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i

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