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Coordination of [{Ti(η 5 -C 5 Me 5 )(μ-NH)} 3 (μ 3 -N)] to Metal Cyclopentadienides: Cyclopentadienyl Azaheterometallocubanes †

✍ Scribed by García-Castro, María; Martín, Avelino; Mena, Miguel; Yélamos, Carlos


Book ID
127236761
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
109 KB
Volume
23
Category
Article
ISSN
0276-7333

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Synthetic and Theoretical Study of the I
✍ María García-Castro; José Gracia; Avelino Martín; Miguel Mena; Josep-M. Poblet; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB 👁 1 views

## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i