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Iodine Attack on the Metalloligand [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]: Surprising Formation of the [Ti3(η5-C5Me5)3I2(μ-NH)3(NH3)]+ Cation

✍ Scribed by María García-Castro; Avelino Martín; Miguel Mena; Josep-M. Poblet; Carlos Yélamos


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
140 KB
Volume
2006
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES


Synthetic and Theoretical Study of the I
✍ María García-Castro; José Gracia; Avelino Martín; Miguel Mena; Josep-M. Poblet; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB 👁 1 views

## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i

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Construction of Heterometallic Cubanes [{Ti 3 Cp \* 3 (m 3 -CR)}(m 3 -O) 3 {Mo(CO) 3 }] (R H, Me; Cp\* h 5 -C 5 Me 5 ) and [{Ti 3 Cp