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[{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]: An Efficient Entry to Single and Double Cube-Type Nitrido Complexes

✍ Scribed by Angel Abarca; Avelino Martín; Miguel Mena; Carlos Yélamos

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
231 KB
Volume
39
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Synthetic and Theoretical Study of the I
Synthetic and Theoretical Study of the Incorporation of Metal Halides in [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]
✍ María García-Castro; José Gracia; Avelino Martín; Miguel Mena; Josep-M. Poblet; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB

## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i

Construction of Heterometallic Cubanes [
Construction of Heterometallic Cubanes [{Ti3Cp*3(μ3-CR)}(μ3-O)3{Mo(CO)3}] (R=H, Me; Cp*=η5-C5Me5) and [{Ti3Cp*3(μ3-N)}(μ3-NH)3{M(CO)3}] (M=Cr, Mo, W); Crystal Structure of [{Ti3Cp*3(μ3-CMe)}(μ3-O)3{Mo(CO)3}]
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Construction of Heterometallic Cubanes [{Ti 3 Cp \* 3 (m 3 -CR)}(m 3 -O) 3 {Mo(CO) 3 }] (R H, Me; Cp\* h 5 -C 5 Me 5 ) and [{Ti 3 Cp