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Redistribution of vibrational energy in naphthalene and anthracene studied in liquid solution

✍ Scribed by N.H. Gottfried; W. Kaiser

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 624 KB
Volume: 101
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87488-0

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✦ Synopsis

The temporal build-up and the decay of vibrational excess population in the electronic ground state is investigated_ CHstretching modes are fast resonantly excited by a picosecond IR pulse and the subsequent flow of energy into several totally symmetric vibrational modes is observed by spontaneous anti-Stokes Raman scattering. Estimated occupation numbers of the monitored modes suggest that the excess energy is redistributed over the many vibrational modes within 5 to 10 ps.

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