Ultrafast intramolecular redistribution and intermolecular relaxation of vibrational energy in large molecules
β Scribed by F. Wondrazek; A. Seilmeier; W. Kaiser
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 546 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0009-2614
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Vibrational energy relaxation and vibrational cooling of polyatomic liquids were studied with the ultrafast infrared-Raman (IR-Raman) technique. In the IR-Raman technique, a type of two-dimensional vibrational spectroscopy, a vibrational transition is pumped with a mid-infrared pulse and the instant
Direct picosecond time resolution of dissipative IVR is reported for the first time. For jet-cooled anthracene with Eeb = 1791 cm -\*\_ rhc urm%-zxed fluorescence displays ;t fast decay of ==75 ps\_ while the reLaxed fluorescence displays a corrc spondin!: rise. The onset for dissipative IVR is rela