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Reaktionen des 1,2,4,5-Tetramethyl-3,5-cyclohexadien-cis-1,2-dicarbonsäureanhydrids im angeregten Zustand

✍ Scribed by Dr. R. N. Warrener; J. B. Bremner

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
119 KB
Volume
78
Category
Article
ISSN
0044-8249

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✍ Heider, Walter ;Hoge, Burghard ;Glemser, Oskar 📂 Article 📅 1978 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 397 KB 👁 1 views

The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained