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Reaktionen des 2,2,2-Trifluor-4,4,5,5-tetrakis(trifluormethyl)-1,3,2λ5-dioxaphospholans

✍ Scribed by Röschenthaler, Gerd-Volker ;Gibson, James Andrew ;Schmutzler, Reinhard

Publisher
Wiley (John Wiley & Sons)
Year
1977
Tongue
English
Weight
422 KB
Volume
110
Category
Article
ISSN
0009-2940

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✍ Heider, Walter ;Hoge, Burghard ;Glemser, Oskar 📂 Article 📅 1978 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 397 KB 👁 1 views

The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained