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Reaktionen des 3,3-Dichlor-1-fluor-5-trifluormethyl-1λ4,2,4,6,3λ5-thiatriazaphosphorin-1-oxids

✍ Scribed by Heider, Walter ;Hoge, Burghard ;Glemser, Oskar

Publisher
Wiley (John Wiley & Sons)
Year
1978
Tongue
English
Weight
397 KB
Volume
111
Category
Article
ISSN
0009-2940

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✦ Synopsis

The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained from 9 and SbF,. Exemplarily the mechanism of the disubstitution followed by fluorine rearrangement is studied using 14, 15 and 16. -The IR, mass, 'H, I9F, and ,'P N M R spectra of the compounds are reported.

📜 SIMILAR VOLUMES

Über das 3,5-Difluor-1,3,5-trioxo-1λ6, 3
Über das 3,5-Difluor-1,3,5-trioxo-1λ6, 3λ6, 5λ6, 2,4,6-trithiatriazin-1-olat-Anion und das 3,5-Difluor-3,5-dioxo-1λ4,3λ6,5λ6,2,4,6-tri-thiatriazin-1-olat-Anion
✍ Wagner, Diec-Lang ;Wagner, Hartmut ;Glemser, Oskar 📂 Article 📅 1975 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 281 KB 👁 1 views

Sulfanurfluorid, \(\left(\mathrm{NSOF}_{3}\right.\), (1) reagiert mit Methanol und Trimethylamin unter Bildung des Tetramethylammonium-3,5-difluor-1,3,5-trioxo-1 \(\lambda^{6}, 3 \lambda^{6}, 5 \lambda^{6}, 2,4,6\)-trithiatriazin-1-olats (2). Dieses Salz ist wasserlöslich, die freie Säure 4 erhält m