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Zur Darstellung des 1,3,3-Trichlor-5-trifluormethyl-1λ4,2,4,6,3λ5-thiatriazaphosphorin-1-oxids, eines sechsgliedrigen S,N,P,C-Ringsystems

✍ Scribed by Heider, Walter ;Glemser, Oskar

Publisher
Wiley (John Wiley & Sons)
Year
1978
Tongue
English
Weight
316 KB
Volume
111
Category
Article
ISSN
0009-2940

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Reaktionen des 3,3-Dichlor-1-fluor-5-trifluormethyl-1λ4,2,4,6,3λ5-thiatriazaphosphorin-1-oxids
✍ Heider, Walter ;Hoge, Burghard ;Glemser, Oskar 📂 Article 📅 1978 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 397 KB

The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained