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Excited-State Reactions of 1,2,4,5-Tetramethyl-3,5-cyclohexadiene-cis-1,2-dicarboxylic Anhydride

✍ Scribed by Dr. R. N. Warrener; J. B. Bremner

Publisher: John Wiley and Sons
Year: 1966
Tongue: English
Weight: 115 KB
Volume: 5
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196603111

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study ( < -30"C)1111. This is best evidenced by the upfield shift of protons H' (by 23Hz) and H5 (by 32Hz) on going from ( 3 ) to ( 5 ) , which simply reflects the increased availability of the lone pair for limited delocalization but is clearly inconsistent with the development of the diamagnetic r