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Reaction of 1,2,4,5-Tetramethyl-1,4-cyclohexadiene with Ozone − Competition between Oxidative Cleavage and Oxydehydrogenation

✍ Scribed by In Chan Jung


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
157 KB
Volume
2001
Category
Article
ISSN
1434-193X

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The reaction of 3-hydroperoxy-4,4,5,5-tetramethyl-3phenyl-1,2-dioxolane, 1, with a series of sulfides (2a ‫ס‬ thioanisole, 2b ‫ס‬ ethyl phenyl sulfide, 2c ‫ס‬ 2-chloroethyl phenyl sulfide, and 2d ‫ס‬ 2-chloroethyl methyl sulfide) at 34ЊC in various solvents yielded the corresponding sulfoxides and 3