𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactivity of cationic 1-substituted dicarbonyl (η5-4-methoxycyclohexadienyl)(triphenylphosphine)iron complexes

✍ Scribed by Nicolas Millot; Catherine Guillou; Claude Thal

Book ID
104258955
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
174 KB
Volume
39
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Nucleophilic addition

of malonate anion to cationic l-substituted (r$-4-methoxycyclohexadienyl)Fe(C0)2PPh3 comp!exes 6e-g proceeds predominantIy at the more substituted cyclohexadienyl terminus to afford l,l-disubstituted (q 4-4-methoxy-2.4cyclohexadiene)Fe(CO)2PPh3 complexes 7e-g in good yields.

📜 SIMILAR VOLUMES

Reaction of cationic 1-substituted (η5-4
Reaction of cationic 1-substituted (η5-4-methoxycyclohexadienyl)(tricarbonyl)iron Complexes with anilines: A revised mechanism
✍ Catherine Guillou; Fabrice Bintein; Jean-Philippe Biron; Claude Thal 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 165 KB

Reaction of p-anisidine 13 or p-bromo orthoanisidine 14 with the new bi-deuterated dienyl complex 12 bearing a leaving group on its side chain affords the mono-deuterated 18a, 19a and the non-deuterated lgb and 19b spiro[1,2,3,4-tetrahydroquinoline-4,1'-cyclohexane] derivatives. The formation of the

First synthesis and reactivity of phosph
First synthesis and reactivity of phosphinite and phosphine bridge chelate dicarbonyl (η5-4-methoxycyclohexadienyl)iron complexes
✍ Nicolas Millot; Catherine Guillou; Claude Thal 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 629 KB

Chelated dicarbonyl 014-4-methoxycyclohcxadiene) iron complexes 6 and 15 which possess a phosphinilc and a phosphme bridge respectively form a new class of iron complexes. Their cations 5 and 16 reacled regioseleclively with nucleophiles in good yields. The observed regioselectivities are unusual fo