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Structure of dicarbonyl(η4-1,5-cyclooctadiene)(triphenylphosphine)ruthenium

✍ Scribed by Ioset, J. ;Mange, V. ;Roulet, R. ;Chapuis, G.

Book ID
114508286
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
313 KB
Volume
47
Category
Article
ISSN
0108-2701

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Reactivity of cationic 1-substituted dic
Reactivity of cationic 1-substituted dicarbonyl (η5-4-methoxycyclohexadienyl)(triphenylphosphine)iron complexes
✍ Nicolas Millot; Catherine Guillou; Claude Thal 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 174 KB

## Nucleophilic addition of malonate anion to cationic l-substituted (r$-4-methoxycyclohexadienyl)Fe(C0)2PPh3 comp!exes 6e-g proceeds predominantIy at the more substituted cyclohexadienyl terminus to afford l,l-disubstituted (q 4-4-methoxy-2.4cyclohexadiene)Fe(CO)2PPh3 complexes 7e-g in good yield