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Chloro(1,5-cyclo­octa­diene)(tri­phenyl­phosphine)­rhodium(I)

✍ Scribed by Horn, Qingyi L. ;Jones, Daniel S. ;Evans, Robin N. ;Ogle, Craig A. ;Masterman, T. Craig


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
170 KB
Volume
58
Category
Article
ISSN
1600-5368

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The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1