1,2,4,5,6,7,8,9-Octachlorotricyclo[5.2.1.02,6]deca-4,8-diene-3,10-diol
✍ Scribed by Gilardi, Richard ;Tang, Datong ;Eaton, Philip E.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 405 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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In order to investigate and probe the possible mechanism of rearrangement of trans-hexaphenyldifluorotricyclooctadiene, (a dimer of fluorotriphenylcyclobutadiene), to pentaphenyldihydrodifluoropentalene via C-F bond migration (Choudhury et al.,2007), a high temperature study of the title compound wa
The title compound, C 18 H 20 ClNO 2 , has been synthesized by the reaction of 4-chlorobenzaldehyde, Meldrum's acid, dimedone and CH 3 NH 3 Cl(NaOAc) in ethanol under microwave irradiation. The pyridone ring adopts a screw-boat conformation and the cyclohexenone ring an envelope conformation.