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First synthesis and reactivity of phosphinite and phosphine bridge chelate dicarbonyl (η5-4-methoxycyclohexadienyl)iron complexes

✍ Scribed by Nicolas Millot; Catherine Guillou; Claude Thal

Book ID
104208010
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
629 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

Chelated dicarbonyl 014-4-methoxycyclohcxadiene) iron complexes 6 and 15 which possess a phosphinilc and a phosphme bridge respectively form a new class of iron complexes. Their cations 5 and 16 reacled regioseleclively with nucleophiles in good yields. The observed regioselectivities are unusual for carbonyl (q5 4-mclhoxycyclohcxadicnyl) iron colnlxmnds.

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