𝔖 Bobbio Scriptorium
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Reactions of singlet oxygen with enol esters

✍ Scribed by Wilson, Stephen L.; Schuster, Gary B.

Book ID
126307094
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
759 KB
Volume
51
Category
Article
ISSN
0022-3263

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## Abstract Photooxygenation of methyl (__E__)‐ and (__Z__)‐2‐methyl‐4‐phenyl‐2‐pentenecarboxylates (__E__‐1, __Z__‐1) afforded the hydroperoxy esters (__R__\*,__S__\*)‐2a and (__S__\*,__S__\*)‐2b through regiospecific and diastereo‐selective ene reaction of singlet oxygen at the α‐methyl group wit