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Role of azide in singlet oxygen reactions: Reaction of azide with singlet oxygen.

โœ Scribed by Noel Hasty; Paul B. Merkel; Phillip Radlick; David R. Kearns


Book ID
108383270
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
192 KB
Volume
13
Category
Article
ISSN
0040-4039

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Singlet oxygen reacts with 1-acetyl-Z-methoxycyclopentene (la) to give the unsaturated hemiperketal 3a. the epoxy-B-diketone% 3a decomposes by an intermolecular oxygen atorn transfer to give -\* Several S-alkoxyenones which are held in the s-trans conformation failed to react with singlet oxygen.