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Reactions of singlet oxygen with biomolecules

✍ Scribed by N. N. Kabal'nova; V. V. Shereshovets; Yu. I. Murinov; D. V. Kazakov; G. R. Abuzarova; G. A. Tolstikov

Book ID
112537612
Publisher
Springer
Year
1996
Tongue
English
Weight
260 KB
Volume
45
Category
Article
ISSN
1573-9171

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Singlet oxygen reacts with 1-acetyl-Z-methoxycyclopentene (la) to give the unsaturated hemiperketal 3a. the epoxy-B-diketone% 3a decomposes by an intermolecular oxygen atorn transfer to give -\* Several S-alkoxyenones which are held in the s-trans conformation failed to react with singlet oxygen.