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Reactions of singlet oxygen with thiophenes

✍ Scribed by Harry H. Wasserman; Wighard Strehlow


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
117 KB
Volume
11
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


The reaction of singlet oxygen with a si
✍ C.N. Skold; R.H. Schlessinger πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 174 KB

Current interest in the reactions of singlet oxygen with heterocyclic systems prompts us to describe some of our own efforts in this area.' The marked reactivity of singlet oxygen with cis-dienes is well documented,' and this behavior suggested that it might be possible to obtain a reaction between

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Reaction of singlet oxygen with Ξ²-alkoxy
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Singlet oxygen reacts with 1-acetyl-Z-methoxycyclopentene (la) to give the unsaturated hemiperketal 3a. the epoxy-B-diketone% 3a decomposes by an intermolecular oxygen atorn transfer to give -\* Several S-alkoxyenones which are held in the s-trans conformation failed to react with singlet oxygen.

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The reaction of singlet oxygen with cis olefins is regioselective and shows a general preference for hydrogen abstraction on the larger alkyl group of the double bond.