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Regioselective reaction of singlet oxygen with cis-alkenes

✍ Scribed by Michael Orfanopoulos; Manolis Stratakis; Yiannis Elemes

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
203 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reaction of singlet oxygen with cis olefins is regioselective and shows a general preference for hydrogen abstraction on the larger alkyl group of the double bond.

πŸ“œ SIMILAR VOLUMES

Reactions of triazolinediones with cis-a
Reactions of triazolinediones with cis-alkenes. A highly regioselective ene reaction
✍ Yiannis Elemes; Manolis Stratakis; Michael Orfanopoulos πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 223 KB

The ene reaction of tiazolinedione with unsymmetrical cis-alkenes is regiospecific and shows a preferential abstraction of the allylic hydrogens on the larger alkyl group of the double bond. ## Triazolinedione (PTAD) undergoes the same type of reactions as singlet oxygen (102). It reacts rapidly